Isomerisation of an intramolecular hydrogen-bonded photoswitch:Protonated azobis(2-imidazole)

Photoisomerisation of protonated azobis(2-imidazole), an intramolecular hydrogen-bonded azoheteroarene photoswitch molecule, is investigated in the gas phase using tandem ion mobility mass spectrometry. The E and Z isomers exhibit distinct spectral responses, with E-Z photoisomerisation occurring over the 360-520 nm range (peak at 460 nm), and Z-E photoisomerisation taking place over the 320-420 nm range (peak at 390 nm). A minor photodissociation channel involving loss of N2 is observed for the E-isomer with a maximum efficiency at 390 nm, blue-shifted by ≈70 nm relative to the wavelength for maximum photoisomerisation response. Loss of N2 is also the predominant collision-induced dissociation channel. Electronic structure calculations suggest that E-isomer photoisomerisation involves S1(ππ∗) excitation, whereas the Z-isomer photoisomerisation involves S2(ππ∗) excitation. Conversion between the E and Z isomers through collisional excitation, which is calculated to occur through both inversion and torsion pathways, is investigated experimentally by colliding the molecular ions with nitrogen buffer gas over a range of electric fields. This study demonstrates the versatility of tandem ion mobility mass spectrometry for exploring the isomerisation of molecular photoswitches initiated by either light or collisions

Model Independent Properties and Cosmological Implications of the Dilaton and Moduli Sectors of 4-d Strings

We show that if there is a realistic 4-d string, the dilaton and moduli supermultiplets will generically acquire a small mass O(m_{3/2}), providing the only vacuum-independent evidence of low-energy physics in string theory beyond the supersymmetric standard model. The only assumptions behind this result are (i) softly broken supersymmetry at low energies with zero cosmological constant, (ii) these particles interact with gravitational strength and the scalar components have a flat potential in perturbation theory, which are well-known properties of string theories. (iii) They acquire a $vev$ of the order of the Planck scale (as required for the correct value of the gauge coupling constants and the expected compactification scale) after supersymmetry gets broken. We explore the cosmological implications of these particles. Similar to the gravitino, the fermionic states may overclose the Universe if they are stable or destroy nucleosynthesis if they decay unless their masses belong to a certain range or inflation dilutes them. For the scalar states it is known that the problem cannot be entirely solved by inflation, since oscillations around the minimum of the potential can lead to a huge entropy generation at late times. We discus some possible ways to alleviate this entropy problem, that favour low-temperature baryogenesis, and also comment on the possible role of these particles as dark matter candidates or as sources of the baryon asymmetry through their decay.Comment: 15 pages,CERN-TH.6958/93,NEIP-93-006, IEM-FT-75/93, Late

Unconventional low-energy SUSY from warped geometry

Supersymmetric models with a warped fifth spatial dimension can solve the hierarchy problem, avoiding some shortcomings of non-supersymmetric constructions, and predict a plethora of new phenomena at typical scales Lambda not far from the electroweak scale (Lambda ~ a few TeV). In this paper we derive the low-energy effective theories of these models, valid at energies below Lambda. We find that, in general, such effective theories can deviate significantly from the Minimal Supersymmetric Standard Model (MSSM) or other popular extensions of it, like the NMSSM: they have non-minimal Kaehler potentials (even in the Mp -> \infty limit), and the radion is coupled to the visible fields, both in the superpotential and the Kaehler potential, in a non-trivial (and quite model-independent) fashion. The corresponding phenomenology is pretty unconventional, in particular the electroweak breaking occurs in a non-radiative way, with tan beta \simeq 1 as a quite robust prediction, while the mass of the lightest Higgs boson can be as high as ~ 700 GeV.Comment: 53 pages, 2 ps figure

Electroweak Symmetry Breaking via UV Insensitive Anomaly Mediation

Anomaly mediation solves the supersymmetric flavor and CP problems. This is because the superconformal anomaly dictates that supersymmetry breaking is transmitted through nearly flavor-blind infrared physics that is highly predictive and UV insensitive. Slepton mass squareds, however, are predicted to be negative. This can be solved by adding D-terms for U(1)_Y and U(1)_{B-L} while retaining the UV insensitivity. In this paper we consider electroweak symmetry breaking via UV insensitive anomaly mediation in several models. For the MSSM we find a stable vacuum when tanbeta < 1, but in this region the top Yukawa coupling blows up only slightly above the supersymmetry breaking scale. For the NMSSM, we find a stable electroweak breaking vacuum but with a chargino that is too light. Replacing the cubic singlet term in the NMSSM superpotential with a term linear in the singlet we find a stable vacuum and viable spectrum. Most of the parameter region with correct vacua requires a large superpotential coupling, precisely what is expected in the ``Fat Higgs'' model in which the superpotential is generated dynamically. We have therefore found the first viable UV complete, UV insensitive supersymmetry breaking model that solves the flavor and CP problems automatically: the Fat Higgs model with UV insensitive anomaly mediation. Moreover, the cosmological gravitino problem is naturally solved, opening up the possibility of realistic thermal leptogenesis.Comment: 27 pages, 3 figures, 1 tabl

Tensor-scalar gravity and binary-pulsar experiments

Some recently discovered nonperturbative strong-field effects in tensor-scalar theories of gravitation are interpreted as a scalar analog of ferromagnetism: "spontaneous scalarization". This phenomenon leads to very significant deviations from general relativity in conditions involving strong gravitational fields, notably binary-pulsar experiments. Contrary to solar-system experiments, these deviations do not necessarily vanish when the weak-field scalar coupling tends to zero. We compute the scalar "form factors" measuring these deviations, and notably a parameter entering the pulsar timing observable gamma through scalar-field-induced variations of the inertia moment of the pulsar. An exploratory investigation of the confrontation between tensor-scalar theories and binary-pulsar experiments shows that nonperturbative scalar field effects are already very tightly constrained by published data on three binary-pulsar systems. We contrast the probing power of pulsar experiments with that of solar-system ones by plotting the regions they exclude in a generic two-dimensional plane of tensor-scalar theories.Comment: 35 pages, REVTeX 3.0, uses epsf.tex to include 9 Postscript figure

Curvatons in Supersymmetric Models

We study the curvaton scenario in supersymmetric framework paying particular attention to the fact that scalar fields are inevitably complex in supersymmetric theories. If there are more than one scalar fields associated with the curvaton mechanism, isocurvature (entropy) fluctuations between those fields in general arise, which may significantly affect the properties of the cosmic density fluctuations. We examine several candidates for the curvaton in the supersymmetric framework, such as moduli fields, Affleck-Dine field, $F$- and $D$-flat directions, and right-handed sneutrino. We estimate how the isocurvature fluctuations generated in each case affect the cosmic microwave background angular power spectrum. With the use of the recent observational result of the WMAP, stringent constraints on the models are derived and, in particular, it is seen that large fraction of the parameter space is excluded if the Affleck-Dine field plays the role of the curvaton field. Natural and well-motivated candidates of the curvaton are also listed.Comment: 34 pages, 5 figure

Forward pi^0 Production and Associated Transverse Energy Flow in Deep-Inelastic Scattering at HERA

Deep-inelastic positron-proton interactions at low values of Bjorken-x down to x \approx 4.10^-5 which give rise to high transverse momentum pi^0 mesons are studied with the H1 experiment at HERA. The inclusive cross section for pi^0 mesons produced at small angles with respect to the proton remnant (the forward region) is presented as a function of the transverse momentum and energy of the pi^0 and of the four-momentum transfer Q^2 and Bjorken-x. Measurements are also presented of the transverse energy flow in events containing a forward pi^0 meson. Hadronic final state calculations based on QCD models implementing different parton evolution schemes are confronted with the data.Comment: 27 pages, 8 figures and 3 table

Search for Doubly-Charged Higgs Boson Production at HERA

A search for the single production of doubly-charged Higgs bosons H^{\pm \pm} in ep collisions is presented. The signal is searched for via the Higgs decays into a high mass pair of same charge leptons, one of them being an electron. The analysis uses up to 118 pb^{-1} of ep data collected by the H1 experiment at HERA. No evidence for doubly-charged Higgs production is observed and mass dependent upper limits are derived on the Yukawa couplings h_{el} of the Higgs boson to an electron-lepton pair. Assuming that the doubly-charged Higgs only decays into an electron and a muon via a coupling of electromagnetic strength h_{e \mu} = \sqrt{4 \pi \alpha_{em}} = 0.3, a lower limit of 141 GeV on the H^{\pm\pm} mass is obtained at the 95% confidence level. For a doubly-charged Higgs decaying only into an electron and a tau and a coupling h_{e\tau} = 0.3, masses below 112 GeV are ruled out.Comment: 15 pages, 3 figures, 1 tabl

Low Q^2 Jet Production at HERA and Virtual Photon Structure

The transition between photoproduction and deep-inelastic scattering is investigated in jet production at the HERA ep collider, using data collected by the H1 experiment. Measurements of the differential inclusive jet cross-sections dsigep/dEt* and dsigmep/deta*, where Et* and eta* are the transverse energy and the pseudorapidity of the jets in the virtual photon-proton centre of mass frame, are presented for 0 < Q2 < 49 GeV2 and 0.3 < y < 0.6. The interpretation of the results in terms of the structure of the virtual photon is discussed. The data are best described by QCD calculations which include a partonic structure of the virtual photon that evolves with Q2.Comment: 20 pages, 5 Figure

Hadron Production in Diffractive Deep-Inelastic Scattering

Characteristics of hadron production in diffractive deep-inelastic positron-proton scattering are studied using data collected in 1994 by the H1 experiment at HERA. The following distributions are measured in the centre-of-mass frame of the photon dissociation system: the hadronic energy flow, the Feynman-x (x_F) variable for charged particles, the squared transverse momentum of charged particles (p_T^{*2}), and the mean p_T^{*2} as a function of x_F. These distributions are compared with results in the gamma^* p centre-of-mass frame from inclusive deep-inelastic scattering in the fixed-target experiment EMC, and also with the predictions of several Monte Carlo calculations. The data are consistent with a picture in which the partonic structure of the diffractive exchange is dominated at low Q^2 by hard gluons.Comment: 16 pages, 6 figures, submitted to Phys. Lett.